Air pockets trapped in the cooling system can cause the engine to overheat. Some cooling systems have air bleed valves built into the system to aid in the removal of air pockets.
Advice: For many cooling systems, the method of removing air pockets is to start the engine and allow it to run with the radiator cap off or loose until all the air escapes from the neck of the radiator. For some systems this method is not sufficient, and the manufacturer has installed air bleed valves usually near or on the thermostat housing.
A low coolant level, a coolant leak (through internal or external leaks), poor heat conductivity inside the engine because of accumulated deposits in the water jackets, a defective thermostat that doesn't open, poor airflow through the radiator, a slipping fan clutch, an inoperative electric cooling fan, a collapsed lower radiator hose, an eroded or loose water pump impeller, or even a defective radiator cap.
* Cooling system leaks -- Loss of coolant because of a coolant leak is probably the most common cause of engine overheating. Possible leak points include hoses, the radiator, heater core, water pump, thermostat housing, head gasket, freeze plugs, automatic transmission oil cooler, cylinder head(s) and block.
Make a careful visual inspection of the entire cooling system, and then PRESSURE TEST the cooling system and radiator cap. A pressure test will reveal internal leaks such as seepage past the head gasket as well as cracks in the head or block. A good system should hold 12 to 15 psi for 15 minutes or more with no loss in pressure. If it leaks pressure, there is an internal coolant leak (most likely a bad head gasket but possibly also a cracked cylinder or engine block).
It is important to pressure test the radiator cap, too, because a weak cap (or one with too low a pressure rating.